Television pictures showed debris from the blast spread out on to the street in front of the building, and Red Cross ambulances on the scene attending to the injured.
The 54-floor Pemex building is 214m (702 ft) tallHundreds of rescuers helped by dogs are searching the building for around 30 people thought to be trapped inside.
Police have cordoned off the streets around the building, which is located in a busy commercial area of Mexico City.
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